Saturday, April 23, 2016

Why ihbarvecnabla for momentum in quantum mechanics, while mvecv in classical mechanics?


I am a little bit confused when thinking of the momentum representation in QM and CM.


In QM, momentum is represented as i, while in classical, momentum is represented as mv.


At least, where does the mass m in CM gone when meets QM please?


Once I saw a sentence like "What quantum theory really unites is matter and information" from Prof. Xiao-Gang Wen's PPT file. Though I do not understand this sentence at all for the moment.



Answer




iħ is the momentum operator. You have to apply it to a wave function to get the actual momentum.


Consider the plane wave solution to the Schrödinger equation: Ψ=eikrωt. Applying the momentum operator gives iħkΨ. You can see the eigenvalue has units of momentum. (If you can't see it, note that kr in the exponent is dimensionless, so clearly k has units of inverse length. ħ has units of angular momentum, so ħk has units of momentum.)


As far as where the mass of the particle factors in, it's in the Schrödinger equation (and thus related to the wave function): iħtΨ(r,t)=[ħ22m2+V(r,t)]Ψ(r,t)


In particular, the classical relationship between momentum and kinetic energy is E=p22m. (That's the same as your mv, for E=12mv2.) Note for the free particle in quantum mechanics, it's the same. EΨ=ħ22m2Ψ=(iħ)22mΨ=p22mΨ


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