Monday, January 1, 2018

bose einstein condensate - What happens to those electrons of BEC cold atoms?


BEC cold atoms occupy the same ground state. But what about the electrons or other fermions of the BEC atoms? Are they in the same state? Do electrons of one atom interact with those of another?



Answer



Yes, the electrons are in the same state and yes they interact (in the sense that identical bosons interact to create a BEC). The explanation is kind of involved.





In a collection of identical atoms, it's not possible for us to distinguish between them. This also applies to their electrons. This is true whether or not the atoms are cold enough to be in a BEC state.


Now the rules of QM state that when you have identical particles (electrons or atoms) you have to symmetrize over them. Thus a literal answer to your question "But what about the electrons or other fermions of the BEC atoms? Are they in the same state?" is "Yes, they're in the same state but this doesn't have anything to do with the BEC state.


Your second question: "Do electrons of one atom interact with those of another?" can be answered similarly. If you consider the electrons as identical particles which must be symmetrized over, then it is impossible to distinguish one electron from the other. Therefore they must all be in the same state. So anything you do to "one" electron will effect all of them. Therefore they do interact; their waveforms are shared.




Now let's be more specific about your questions in terms of the nature of the BEC state. Consider just a single atom. It is described by a wave function. As the atom is placed in a cooler environment it loses energy. This loss of energy changes the shape of the wave function. It makes the wave function bigger. The wavelength for the wave function of a gas atom is called the "Thermal de Broglie wavelength". The formula is:
$$\lambda_T = \frac{h}{\sqrt{2\pi m k T}}$$
where $h$ is the Planck constant, $k$ is the Boltzmann constant, $T$ is the temperature, and $m$ is the mass of the gas atom.


The thing to note about the above formula is that as the temperature gets lower, the wavelength $\lambda_T$ gets bigger. When you reach the point that the wavelengths are larger than the distances between atoms, you have a BEC. The reference book I've got is "Bose-Einstein Condensation in Dilute Gases" by C. J. Pethick and H. Smith (2008) which has, on page 5:



"An equivalent way of relating the transition [to BEC] temperature to the particle density is to compare the thermal de Broglie wavelength $\lambda_T$ with the mean interparticle spacing, which is of the order $n^{-1/3}$. ... At high temperatures, it is small and the gas behaves classically. Bose-Einstein condensation in an ideal gas sets in when the temperature is so low that $\lambda_T$ is comparable to $n^{-1/3}$."




When the wavelengths are longer than the inter-particle distances, the combined wave function for the atoms (which one must symmetrize by the rules of QM) becomes "coherent". That is, one can no longer treat the wave functions of different atoms as if they were independent.




To illustrate the importance of this, let's discuss the combined wave function of two fermions that are widely separated with individual wave functions $\psi_1(r_1)$ and $\psi_2(r_2)$. For fermions, the combined symmetrized wave function is:
$$\psi(r_1,r_2) = (\psi_1(r_1)\psi_2(r_2) - \psi_1(r_2)\psi_2(r_1))/\sqrt{2}.$$ Now the Pauli exclusion principle says that exchanging two fermions causes the combined wave function to change sign. That's the purpose of the "-" in the above equation; swapping $r_1$ for $r_2$ gives you negative of the wave function before the change.


Another, more immediate, way of stating the Pauli exclusion principle is that you can't find two fermions in the same position. Thus we must have that $\psi(r_a,r_a) = 0$ for any fermion wave function where $r_a$ can be any point in space. But for the case of the combined wave function of two waves that are very distant from one another there is no point $r_a$ where both of the wave functions are not zero (that is, the wave functions do not overlap). Thus the Pauli exclusion principle doesn't make a restriction on the combined wave function in the sense of excluding the possibility that both electrons could appear at the same point. That was already intrinsically required by the fact that the two wave functions were far apart.


Now I used the above argument about "far apart fermions" because the Pauli exclusion principle has a more immediate meaning to a lot of people than the equivalent principle in bosons. The same argument applies to bosons, but in reverse. Bosons prefer to be found near one another, however if we write down the combined wave function for two widely separated bosons, there is still a zero probability of finding both bosons at the same location. Again the reason is the same as in the fermion case: $\psi_1(r_b)$ is only going to be nonzero in places where $\psi_2(r_b)$ is already zero. The bosons are too far apart to interact (in the sense of changing the probability of finding both at the same point from what you'd otherwise expect classically).


Another way of saying all this is that in QM, there is no interaction between things except if their wave functions overlap in space. You use the thermal de Broglie wave function to determine how big a wave function has to be. If the atoms are closer than that, they're interacting in the sense of bose (or fermi) condensates.




So let's apply our understanding to the question "do the electrons interact" in a BEC. Consider the $\lambda_T$ formula to the electron. Since $m$ appears in the denominator, replacing the atom with the electron decreases $m$ by a factor of perhaps 3 or 4 orders of magnitude. This increases $\lambda_T$ by perhaps 2 orders of magnitude. Therefore, any gas which is cold enough to be a BEC will be composed of electrons that are much more than cold enough to also be coherent.



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