Sunday, September 29, 2019

thermodynamics - Is a plasma a distinct phase of matter?


Long ago I learned that a plasma was a distinct state of matter after solid, liquid and gas, and also that it was achieved by imparting heat to a the matter. But most references describe a plasma as an ionized gas. So I'm having trouble understanding, what then, does it mean to be a distinct phase of matter? Is ionization, as opposed to heat, all that's required to make a gas a plasma? If so, what makes a plasma more distinguished than, say, an ionized liquid?



Answer



For clarity, there is a common misconception about plasma here. Plasma when being introduced for the first time to someone who doesn't know what it is, it is called "The fourth state of matter" which is an inaccurate description of it. Since this term is used for introducing some one to plasma, it is no big deal.


When a material changes from a distinct phase to another, it goes through a physical process called phase transition. When gas becomes plasma, it doesn't go through the standard phase transition. Hence plasma-in a general sense-can't be regarded as a distinct phase as solid, liquid and gas phases. It is a phase of the gaseous state. In certain rare cases however, transition from gas to plasma can be described as phase transition.


Plasma by definition is a mixture of free electrons and their ions (possibly negative ions). You need enough energy to liberate electrons from atoms. Roughly speaking, When you put that energy in a solid, energy might be dissipated as heat. If you put that energy in a liqued, energy might be dissipated in vaporization. If you put it in a gas it goes into breaking atoms and molecules (creating plasma). The following figure makes it clearer


enter image description here


Hopefully that was useful


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