Friday, August 1, 2014

statistical mechanics - Physical intuition for independence of components of velocity in derivation of Maxwell–Boltzmann distribution



Maxwell derived the shape of the probability distribution of velocity of gas particles by starting with just two assumptions.


These are:




  1. The probability distribution is rotation invariant.




  2. The components (of velocity of a gas particle) in the direction of the coordinate axes are statistically independent.





And the rest is lovely deduction, but I found that as a layman I don't have any physical intuition as to why the second assumption is plausible. Is there an intuitive explanation behind the second assumption? If not, is there a way to derive the second assumption from a set of more plausible-looking assumptions?




No comments:

Post a Comment

classical mechanics - Moment of a force about a given axis (Torque) - Scalar or vectorial?

I am studying Statics and saw that: The moment of a force about a given axis (or Torque) is defined by the equation: $M_X = (\vec r \times \...