To quantize a scalar field theory with the action:
S=∫dDxL(ϕ,∂μϕ)=∫dx0L(ϕ,∂0ϕ)
we promote ϕ(→x) and π=δLδ(∂0ϕ)=π(→x) to be field operator at fixed time x0 (with the canonical commutation relation [ϕ(→x),π(→y)]=δD−1(→x−→y)), then we use the classical equation of motion to find ϕ and π at all time.
What principles lie behind this? Why can we assume that the field operators satisfy the classical equation of motion?
By example if we have a classical theory with S=∫dtL(ϕ,∂tϕ), momentum π=δLδ(∂tϕ) hamiltonian H=πϕ−L, the classical equation of motion is:
dϕdt=δLδ(∂tϕ)
When we do the canonical quantization, we promote [ϕ,π]=δ(→x−→y) and the equation of motion for ϕ is dϕdt=i[H,ϕ]
Why should i[H,ϕ] has the same form as δLδ(∂tϕ)? This fact comes from where?
Answer
How to see it in canonical quantization: All operators O in a quantum theory fulfill the Heisenberg equations of motion ddtO(t)=i[H,O(t)]
How to see it in path integral quantization: Write ϕ′(x)=ϕ(x)+ϵδ(y−x) and observe the path integral measure is invariant under this. Expand the integrand to first order in ϵ, and deduce ∫(δSδϕ(x)+J(x))eiS[ϕ]+JϕDϕ=0
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