The higher the number of the shell (n), the higher is the energy level of the electron. However, why was it necessary to have negative values. So for example, when n=1, the energy could be 5eV and for n=2, 6eV... having positive values could also have supported the idea that as n increases, energy of electron increases. What is the point of having negative numbers, does it somehow aid calculations?
Answer
We say that a free, unbound electron has zero energy (that's convention, you could just as well put another number there). This means that the level n=∞ is fixed at E∞=0eV. Since the other levels lie lower, i.e. possess less energy, this forces all other bound states to have negative energies - which then represent that we need to add energy to make the bound state free, which corresponds to raising its energy to zero.
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