Thursday, April 27, 2017

statistical mechanics - How to obtain the Bose-Einstein distribution from the canonical ensemble?


In the wikipedia page


https://en.wikipedia.org/wiki/Fermi%E2%80%93Dirac_statistics#Canonical_ensemble



the Fermi-Dirac distribution is obtained from the canonical ensemble in the following manner:


The average occupation number is given by


ˉni=n1,n2,...nieβ(n1E1+n2E2+...)n1,n2,...eβ(n1E1+n2E2+...)


where the summation is over the sets of nr that satisfy nr=N, being N the total number of particles in the system. The derivation followed in Wikipedia then separates the state of energy Ei and calls


ˉni=ninieβniEiZi(Nni)nieβniEiZi(Nni)


where Zi(Nni)=n1,nn,...eβ(n1E1+n2E2+...). The summation here does not consider the state ni. Since for the Fermi-Dirac case ni=0,1, it is possible to write the summation easily (it has only two terms) to obtain


ˉni=1[Zi(N)/Zi(N1)]eβEi+1


which will, in turn, result in the Dirac-Fermi distribution once the ratio between the partition functions is related to the chemical potential.


Now, I'm trying to follow the same procedure to obtain the Bose-Einstein distribution but in this case ni can vary between 0 and and the summation cannot be done in any direct way I could think of. How can I approach this?


Thank you very much.




Answer



The expression: ˉni=ninieβniEiZi(Nni)nieβniEiZi(Nni)

can be rewrite in a usual for statphysics manner: ˉni=1β Ln Z(N)Ei
We denoted denominator as Z(N) -canonical partition function of the system (do not confuse it with Zi(N) - partition function with "punctured" i-th one particle state. Then, denoting zi=eβμ -"punctured" fugacity, we can write: Z(N)=ni=Nni=0 eβniEiZi(Nni)=ni=Nni=0 (eβEi)ni(1zi)Nni=
=zNini=Nni=0 (zieβEi)ni
Then, sequentially we write down the sum formulae for a finite geometric series, take the logarithm, tend N to infinity, and differentiate by Ei. Finally, acting in the wiki spirit, we replace μi =μ


PS. After I wrote this answer, I looked at the link in Wikipedia, it turns out the derivation of the B-E distribution by a similar method is in the same link ((Reif 1965) on p. 342


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