Sunday, March 12, 2017

quantum mechanics - Hydrogen radial wave function infinity at $r=0$


When trying to solve the Schrödinger equation for hydrogen, one usually splits up the wave function into two parts:



$$\psi(r,\phi,\theta)= R(r)Y_{l,m}(\phi,\theta).$$


I understand that the radial part usually has a singularity for the 1s state at $r=0$ and this is why you remove it by writing:


$$R(r) = \frac{u(r)}{r}$$


But what is the physical meaning of


$$R(r=0) = \infty~?$$


Wouldn't this mean that the electron cloud is only at the centre of the atomic nucleolus?




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