why do we have minimum deviation angle in a prism? I mean why does the angle of emergence first decreases, attains a minimum value and then increases.why?
Answer
I attempt to explain the presence of a minimum mathematically instead of experimentally.
The light ray travels through air and hits the glass prism, at an angle θ1 (the angle of incidence) to the normal of the glass boundary.
When the ray is in the glass, the angle of the ray changes to θ2 (the angle of refraction), to the normal of the glass boundary. The two angles are related by Snell's Law, such that: sinθ1sinθ2=nglassnair
Assuming you know θ1, nglass, and nair, then you can find out θ2.
Then, when the light ray (which is currently inside the glass) hits the air boundary, there is a new angle of incidence θ3. θ3 depends on the the angle at the top of the prism, A. sum of angles in triangle=180∘
We want to know the angle of refraction θ4. So we apply Snell's Law again: sinθ4sinθ3=nglassnair
From geometry, angle of deviation=θ1−θ2+θ4−θ3

To minimize angle of deviation, assuming A is constant, we need to minimize θ1+θ4.
We can find θ4 in terms of θ1. Equating the two Snell's Law equations, sinθ4sinθ3=sinθ1sinθ2
Substituting θ3=A−θ2, sinθ4sin(A−θ2)=sinθ1sinθ2
Substituting θ2=sin−1(nair∗sinθ1nglass), θ4=sin−1((sinAtan(sin−1(nair∗sinθ1nglass))−cosA)∗sinθ1)
Because I'm not good at math, this is where my analysis ends, and WolframAlpha begins. Punching in arbitrary values for the angle of prism, and for refractive indeces, we find the values of θ1 such that we minimize θ1+θ4.
The very fact that WolframAlpha can find minima for θ1+θ4 means that there are values of θ1 such that angle of deviation has minima.
Notice that the values of the minimum are offset from the value of θ by a constant amount every time. This constant amount happens to be θ1 such that θ1=θ4. So, this shows that the angle of deviation is minimum only for θ1=θ4.
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