Tuesday, July 25, 2017

quantum mechanics - Von Neumann entropy in terms of the mutual overlap?


I have N pure, but nonorthogonal, states |ψn with density matrix ρn=|ψnψn|.


Say we call the the total density matrix ρ=1Nnρn.


Are there any formulas to calculate Svn[ρ]=Tr[ρlogρ] solely from the overlaps ψn|ψm (and the fact that all individual states are pure)? Gram-Schmidt orthogonalization might be a possibility but perhaps there is an easier way/existing result?


Intuitively it would seem at first that knowledge of the Tr[ρnρm]=|ψn|ψm|2 would be sufficient because the mixing between the states is noncoherent, but is this true?



Answer



Let us denote the overlap matrix by O, this is, Onm=ψn|ψm. Then, SvN(ρ)=SvN(O) .

More generally, O has the same non-zero eigenvalues as ρ, so any function of the eigenvalues (which is insensitive to zero eigenvalues) can be evaluated on O instead of ρ.


This can be seen by defining a matrix X whose columns are the states |ψn, i.e. Xkn=k|ψn. Then, ρ=XX, while O=XX. However, two matrices AB and BA always have the same non-zero eigenvalues, and thus, the non-zero eigenvalues of ρ and O are the same.



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