A form of the Schrödinger equation is
[−ℏ22m∇2+V(→r,t)]Ψ=iℏ∂∂tΨ
The bracketed term is of course the Hamiltonian, and the whole equation can hence be written as
ˆHΨ=iℏ∂∂tΨ
My question is, is there a existing/named operator represented by iℏ∂∂t? That is, can we further rewrite the equation as
ˆHΨ=ˆΘΨ
For some predefined operator ˆΘ=iℏ∂∂t?
Answer
No, it is not an operator, at least with the same status as that of the Hamiltonian operator! The states are described by vectors in a Hilbert space, in this case L2(R3), i.e. functions ψ=ψ(x) with integrable squared absolute value: ∫R3|ψ(x)|2d3x<+∞. Operators representing observables act in that space A:ψ↦Aψ where Aψ∈L2(R3).
Regarding Schroedinger equation, the situation is different. In that case one considers vector-valued curves R∋τ↦ψτ∈L2(R3) representing the temporal evolution of an initially given state ψ0.
The equation says that the time derivative (actually computed in the topology of the Hilbert space) of that curve at a given time t: dψtdt
Hence d/dt (with some possible constant factor) cannot be considered an operator in the Hilbert space of the theory, L2(R3), as it acts on curves valuated in that Hilbert space. Obviously this space of curves enjoys a structure of complex linear space and d/dt is an operator with respect to that vector space structure, but that structure does not play any role in QM.
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