Saturday, October 18, 2014

quantum mechanics - An operator on the other side of the Schrödinger equation


A form of the Schrödinger equation is


[22m2+V(r,t)]Ψ=itΨ


The bracketed term is of course the Hamiltonian, and the whole equation can hence be written as


ˆHΨ=itΨ



My question is, is there a existing/named operator represented by it? That is, can we further rewrite the equation as


ˆHΨ=ˆΘΨ


For some predefined operator ˆΘ=it?



Answer



No, it is not an operator, at least with the same status as that of the Hamiltonian operator! The states are described by vectors in a Hilbert space, in this case L2(R3), i.e. functions ψ=ψ(x) with integrable squared absolute value: R3|ψ(x)|2d3x<+. Operators representing observables act in that space A:ψAψ where AψL2(R3).


Regarding Schroedinger equation, the situation is different. In that case one considers vector-valued curves RτψτL2(R3) representing the temporal evolution of an initially given state ψ0.


The equation says that the time derivative (actually computed in the topology of the Hilbert space) of that curve at a given time t: dψtdt

equals the action of an operator on ψt at that time i1Hψt
To compute (2), we need to know just the vector ψt. Instead, to compute (1) we need to know the curve τψτ in a neighborhood of t!


Hence d/dt (with some possible constant factor) cannot be considered an operator in the Hilbert space of the theory, L2(R3), as it acts on curves valuated in that Hilbert space. Obviously this space of curves enjoys a structure of complex linear space and d/dt is an operator with respect to that vector space structure, but that structure does not play any role in QM.


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