Thursday, November 16, 2017

quantum mechanics - Mean field equations in the BCS theory of superconductivity


In BCS theory, one takes the model Hamiltonian



kσ(Ekμ)ckσckσ+kkVkkckckckck


This Hamiltonian clearly conserves particle number. Thus, we expect the ground state to have a definite particle number. It's possible the ground state is degenerate, but that could be lifted by perturbing μ.


Then, one makes a mean field approximation. One replaces ckckckck


with ckckckck+ckckckckckckckck


This doesn't make any sense to me. This seems to be saying that we know the terms ckck and ckck don't fluctuate much around their mean values. But we also know that in the actual ground state, the mean values are given by ckck=ckck=0 since the ground state will have definite particle number. Thus the fluctuations about the mean value aren't small compared to the mean value.


How can this mean field treatment be justified?




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