Suppose, I am taking measurement with a scale whose least deviation is 1mm. the length of something seems to lie between 44mm to 45mm. But my instinct says, it's 44.7mm. So, the question is I should report 44.7+-0.5mm or 44.5+-0.5mm or something else?
Answer
There are a few different concepts we need to cover here.
First - the difference between precision and accuracy. Precision tells me the number of digits I can write down: in your case, you might be able to estimate that the number is close to 44.7 and you might even believe your ability to interpolate is such that the answer is 44.7 ± 0.1 mm. Of course, when you are reading an analog scale, you usually need to worry about parallax: depending on where your eye is with respect to the alignment of the measurement with the scale, you may get an error. Old analog meters often addressed this by putting a mirror behind the scale: you had to line up your eye such that the reflection of the needle fell right behind the needle - this is how you would minimize the parallax error.
The second issue is accuracy: when the supplier of your analog device (a ruler, in this case) put markings on the ruler, they did so with a certain tolerance. In a rare case, this tolerance might be noted on the ruler - most of the time, you assume it is "as good as the divisions on the ruler". In other words, when a ruler is marked in mm, you can reasonably assume that a measurement of 44 mm is closer to 44 mm than it is to 45 mm or 43 mm. But the manufacturer usually doesn't claim that the line that is drawn at 44 mm is actually drawn at 44.0 mm
When you try to interpolate, you are in effect assuming that 44 = 44.0 ; while that may sometimes be true (it would have to be independently confirmed), it won't always be. And if you start quoting numbers like 44.7 you are in fact claiming that your measuring instrument has accuracy beyond its markings.
In summary - there are actually multiple sources of error that affect your measurement. There is error aligning the ruler (including parallax), error reading the ruler (especially interpolating between markings), and errors in the ruler itself. Proper error estimation accounts for all these things.
If you cannot fully analyze all these sources of error, it is a useful shortcut to round to the nearest whole marking. When you add digits without knowing the accuracy of your ruler, you may be falsely claiming a precision that is not there.
To clarify: I recommend in your case to quote 45 +- 0.5 mm
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