Why is the work done on a charge calculated from infinity to a point? Why not from one particular point to other?
Answer
Consider the form of the potential energy between two point charges in the case that I use a reference distance $r_0$ as the zero (written here in SI units). $$ U_{r_0} = \frac{q_1 \,q_2}{4 \pi \epsilon_0} \left( \frac{1}{r} - \frac{1}{r_0} \right) \;.$$ This is quite general, but it will get to be very messy to write down and manipulate very quickly indeed. It also means that the sign of the energy depends on the the relative sign of the charges and the relative size of $r$ and $r_0$
Now, the special case of taking $r_0$ as arbitrarily distant, gets us the familiar form \begin{align*} U_\infty &= \lim_\limits{r_0 \to \infty} U_{r_0}\\ &= \frac{q_1 \,q_2}{(4 \pi \epsilon_0) r} \;, \end{align*} which is algebraically simpler and the sign of which can be known at any distance just from the relative sign of the charges.
The conventional form is simply easier to use in the majority of cases.
But it gets better, because the same kind of consideration applies to Newtonian gravitation, and the convention of zero energy at infinite remove means that the total energy bound bodies is negative while that of free bodies is positive (with zero the parabolic edge case).
It really is a natural choice after you've looked at the ways you're going to be using the quantity.
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