There is section in Sakurai's "Modern Quantum Mechanics 2nd edition" page 188 that is quite confusing as to what he is doing. In the section on "Quantum Statistical Mechanics" he defines a quantity σ=−tr(ρlnρ), where the entropy is given as S=kσ. Then in order to maximize σ he states the following "Let us maximize σ by requiring that δσ=0. (1)
However, we must take into account the constraint that the ensemble average of H has a certain prescribed value. In the language of statistical mechanics, [H] is identified with the internal energy per constituent, denoted by U: [H]=tr(ρH)=U. In addition, we should not forget the normalization constraint ∑kρkk=1 (where ρ is the density operator). So our basic task is to require (1) subject to the constraints δ(H)=∑kδρkkEk=0 and δ(trρ)=∑kδρkk=0.
We can most readily accomplish this by using Lagrange multipliers. We obtain ∑kδρkk[(lnρkk+1)+βEk+γ]=0 which for an arbitrary variation is possible only if ρkk=exp(−βEk−γ−1)."
Question: What is the reasoning for the requirement (1) in order to maximize σ, and how are the constraints obtained?
No comments:
Post a Comment