Wednesday, August 30, 2017

quantum mechanics - Density operator as a function of time


Given the density operator ρ=iwi|αiαi|, how does the density operator change with time. Apparently I should get iρt=iwi(H|αi(t)αi(t)||αi(t)αi(t)|H). I am having difficulty getting this, it seems that I have to use Shrodingers equation on the (|αα|) since the intial population wi is constant in time, but I'm not sure how to differentiate this since α| as I understand is a bra which is a functional in a sense, how does the product rule for differentiation apply then in this case?


Thanks.



Answer



Start with iddt|α=H|α and take the adjoint iddtα|=α|H where H=H has been used. Then simply use the product rule: iddt[|αα|]=[iddt|α]α|+|α[iddtα|],=[H|α]α||α[α|H].



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