Saturday, January 25, 2020

quantum mechanics - What is the reason that relativistic corrections for hydrogen atom work?



Here I cite part from Sidney Coleman's lectures on Quantum Field Theory:



It is a phenomenal fluke that relativistic kinematic corrections for the Hydrogen atom work. If the Dirac equation is used, without considering multi-particle intermediate states, corrections of $O \big(\frac{v}{c}\big)$ can be obtained. This is a fluke caused by some unusually low electrodynamic matrix elements.



What is the fluke about? Also, how can one justify the usage of Pauli-Schrodinger type equations that comes from first quantization of Dirac's equation? Schrodinger's equation is universal postulate valid for any quantum theory, and is equation for wave functionals in field theory. Could one go from non-relativistic QED field theory and then justify the usage of Pauli equation in which $\psi$ is interpreted as "wave function" in certain kinematical conditions (approximation)?




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