Both $\hat{a}^\dagger\hat{a}$ and $\hat{a}\hat{a}^\dagger$ are Hermitian, how do we know which one represents the particle number?
Answer
We require that the number operator have the following property:
$$\hat n |0\rangle = 0.$$
We know that
$$\hat a |0\rangle = 0$$
and we know that
$$\hat a |1\rangle = |0\rangle$$
and we know that
$$\hat a^{\dagger} |0\rangle = |1\rangle. $$
Thus, it follows that
$$\hat a \hat a^{\dagger} \ne \hat n$$
since
$$\hat a \hat a^{\dagger} |0\rangle = \hat a|1\rangle \ne 0.$$
Now, it remains to be shown that
$$\hat a^{\dagger}\hat a = \hat n. $$
Can you take it from here?
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