Absence of magnetic charges is reflected in one of Maxwell's fundamental equations: div→B=0.
Noticing, that vector →A and scalar ϕ potentials, as well as electric current density →j and charge density ρ, form a 4-vector in Minkovsky space-time. Therefore, Maxwell's equations can be expressed in a covariant form, using d'Alembertian: ∇μ∇μAν=jνϵ0.
If magnetic monopols exist, Maxwell's equation (1) will look as: div→B=μ0cρmagnet.
As the divergence of →B isn't equal to zero, it impossible to introduce concept of vector potential. Thus, the equation in the form of (4) will not be possible to express.
Answer
Another option, besides modifying the potential Aμ=(Ai,ϕ) in some way, is to introduce another 4-potential Cμ=(Ci,ψ). Then the electric and magnetic field are given by E=−∇×C−∂A∂t−∇ϕ
More on this 2-potential approach can be found here: http://arxiv.org/abs/math-ph/0203043
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